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Why gases at high pressure and low temperature show large deviation from ideal gas behaviour?
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Under high pressure and low temperature condition, the volume of a given mass of a gas is very small and molecules are closely packed. As a result, the intermolecular interactive forces become significant and cannot be neglected. Moreover as compared to total volume the actual volume occupied by the gas molecules is also not negligible. Due to these two factors gases show large deviation from ideal gas behaviour under high pressure and low temperature condition.