In square planar complexes like [Ni(CN)₄]²⁻, the hybridization involved is dsp², whereas tetrahedral complexes involve the hybridization of one s and three p orbitals. Nickel in [Ni(CN)₄]²⁻ is in the +2 oxidation state with the electronic configuration 3d⁸.
How does the hybridization differ in the square planar complex [Ni(CN)₄]²⁻ compared to tetrahedral complexes?
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The hybridization in the square planar complex [Ni(CN)₄]²⁻ differs from tetrahedral complexes. In [Ni(CN)₄]²⁻, nickel is in the +2 oxidation state with the electronic configuration 3d⁸. The hybridization scheme involves dsp² hybridization, where one d orbital, one s orbital, and two p orbitals of nickel form four equivalent hybrid orbitals. Each cyanide ion donates a pair of electrons for bonding. This hybridization results in a square planar geometry. In contrast, tetrahedral complexes typically involve sp³ hybridization. The difference lies in the type and number of orbitals involved in the hybridization process, leading to distinct geometries.