The spectrochemical series is an experimentally determined sequence based on the absorption of light by complexes with various ligands. It provides insights into the ligand’s ability to cause crystal field splitting.
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The spectrochemical series is an experimentally determined sequence that ranks ligands based on their ability to cause crystal field splitting in coordination complexes. Ligands are categorized as strong-field or weak-field ligands, influencing the magnitude of crystal field splitting and determining the electronic structure of the complex. The series is established through experimental observations of the absorption of light by complexes with different ligands. The ligands that cause larger crystal field splittings are considered strong-field ligands, while those leading to smaller splittings are classified as weak-field ligands. The spectrochemical series aids in predicting the magnetic and optical properties of coordination compounds.