Class 12 Physics
CBSE and UP Board
Atoms
Chapter-12 Exercise 12.7
NCERT Solutions for Class 12 Physics Chapter 12 Question-7
(a) Using the Bohr’s model calculate the speed of the electron in a hydrogen atom in the n = 1, 2, and 3 levels. (b) Calculate the orbital period in each of these levels.
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Ans (a).
Let ν1 be the orbital speed of the electron in a hydrogen atom in the ground state level, n1 = 1. For charge (e) of an electron, ν1 is given by the relation,
ν1 = e²/n1 4π ε0 (h/2π) = e²/2 n1ε0h
Where, e = 1.6 x 10⁻19 C
ε0 = Permittivity of free space = 8.85 x 10⁻12 N-1 C2 m2
h = Planck’s constant = 6.62 x 10⁻³⁴ Js
Therefore, ν1 = (1.6 x 10⁻19 )2 /2 x (8.85 x 10⁻12) x (6.62 x 10⁻³⁴)
= 0.0218 x 10⁸ = 2.18 x 10⁶ m/s
For level n2= 2 ,we can write the relation for the corresponding orbital speed as:
ν2 = = e²/2 n2ε0h = (1.6 x 10⁻19 )2 /2 x 2 x(8.85 x 10⁻12) x (6.62 x 10⁻³⁴)
=1.09 x 10⁶ m/s
For level n3= 3 ,we can write the relation for the corresponding orbital speed as:
ν3 = = e²/2 n3ε0h = (1.6 x 10⁻19 )2 /2 x 3 x (8.85 x 10⁻12) x (6.62 x 10⁻³⁴)
=7.27 x 10⁵ m/s
Hence, the speed of the electron in a hydrogen atom in n = 1, n=2, and n=3 is 2.18 x 106 m/s, 1.09 x 106 m/s, 7.27 x 105 m/s respectively.
Ans (b).
Let T1 be the orbital period of the electron when it is in level n1 = 1.
Orbital period is related to orbital speed as:
T1 = 2π r/ν1
Where,r1 = Radius of the orbit =( n1)²h²ε0/πme²
h = Planck’s constant = 6.62 x 10⁻³⁴ Js and
e = Charge on an electron = 1.6 x 10⁻19 C.
ε0 = Permittivity of free space = 8.85 x 10⁻12 N⁻1C2 m⁻²
m = Mass of an electron = 9.1 x 10⁻31 kg
Therefore, T1 = 2π r1/ν1
= 2π x (1)² x (6.62 x 10⁻³⁴)² x (8.85 x 10⁻12)/[(2.18 x 10⁶) x π x ( 9.1 x 10⁻31) x (1.6 x 10⁻19)² ]
= 15.27 x 10⁻¹⁷ = 1.527 x 10⁻¹⁶ s
For level n2 = 2, we can write the period as:
T2 = 2π r2/ν2
Where, r2 = Radius of the electron in n2 = 2
= (n2)²h²ε0/πme²
Therefore,T2 =2π r2/ν2
=2π x (2)² x (6.62 x 10⁻³⁴)² x (8.85 x 10⁻12)/[(1.09 x 10⁶) x π x ( 9.1 x 10⁻31) x (1.6 x 10⁻19)² ]
=1.22 x 10⁻¹⁵ s
For level n3 = 3, we can write the period as:
T3 = 2π r3/ν3
Where, r3 = Radius of the electron in n3 = 3
= (n3)²h²ε0/πme²
Therefore,T3 =2π r3/ν3
=2π x (3)² x (6.62 x 10⁻³⁴)² x (8.85 x 10⁻12)/[(7.27 x 10⁵) x π x ( 9.1 x 10⁻31) x (1.6 x 10⁻19)² ]
=4.12 x 10⁻¹⁵ s
Hence, the orbital period in each of these levels is 1.527 x 10⁻¹⁶, 1.22 x 10⁻¹⁵ s, and 4.12 x 10⁻¹⁵ s respectively.