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What is the significance of the high melting points observed in the transition metals belonging to the 3d, 4d, and 5d series, and what contributes to this phenomenon?

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The high melting points of transition metals in the 3d, 4d, and 5d series are attributed to the involvement of a greater number of electrons from (n-1)d, in addition to the ns electrons, in the interatomic metallic bonding. The presence of one unpaired electron per d orbital is particularly favorable for strong interatomic interaction.

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  1. The high melting points observed in the transition metals belonging to the 3d, 4d, and 5d series are significant due to the involvement of a greater number of electrons from (n-1)d in addition to the ns electrons in interatomic metallic bonding. The strong metallic bonding results from the effective overlap of d orbitals, contributing to a robust crystal lattice. In any row, the melting points of these metals rise to a maximum at d⁵, except for anomalies like Mn and Tc. This phenomenon indicates that having one unpaired electron per d orbital is particularly favorable for strong interatomic interaction, explaining the high melting points observed in the transition metal series.

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