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Nucleophilic addition involves attack by a nucleophile on the electrophilic carbon of the carbonyl group, changing the hybridization of the carbonyl carbon from sp² to sp³. This process forms a tetrahedral alkoxide intermediate that captures a proton to yield the ...

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The absence of intermolecular hydrogen bonding in aldehydes and ketones contributes to their lower boiling points compared to alcohols. Alcohols exhibit stronger intermolecular forces due to hydrogen bonding.

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Boiling points of aldehydes and ketones are higher than hydrocarbons and ethers due to dipole-dipole interactions. Weak molecular association in aldehydes and ketones results in these higher boiling points.