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Chandu

The Reimer-Tiemann reaction involves treating phenol with chloroform in the presence of sodium hydroxide, resulting in the introduction of a -CHO group at the ortho position of the benzene ring. The intermediate benzal chloride is hydrolyzed to produce salicylaldehyde.

Gk

Phenoxide ion, produced by treating phenol with sodium hydroxide, undergoes electrophilic substitution with carbon dioxide in Kolbe’s reaction, forming ortho hydroxybenzoic acid as the main product. The phenoxide ion is more reactive than phenol due to its enhanced nucleophilicity.