The magnetic moment of coordination compounds is determined through magnetic susceptibility experiments, providing insights into the number of unpaired electrons and the structures adopted by metal complexes.
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Metal atoms or ions, influenced by ligands, undergo hybridization of their (n-1)d, ns, np orbitals to produce a set of equivalent orbitals with defined geometries (e.g., octahedral, tetrahedral). These hybridized orbitals then overlap with ligand orbitals to facilitate bonding.