Aldehydes are more reactive due to both steric and electronic reasons. Sterically, the hindered approach of nucleophile to the carbonyl carbon is less in aldehydes. Electronically, aldehydes are more reactive because two alkyl groups in ketones reduce the electrophilicity of ...

The carbonyl carbon is sp²-hybridized, forming three sigma (σ) bonds. It also forms a π-bond with oxygen by overlap with the p-orbital of carbon.

Aromatic aldehydes are named as substituted benzaldehydes. The IUPAC-accepted common name for the simplest aromatic aldehyde is benzenecarbaldehyde, but benzaldehyde is also accepted by IUPAC.

For cyclic ketones, numbering starts from the end nearer to the carbonyl group. The carbonyl carbon is assigned position one in the naming of cyclic ketones.

IUPAC names of aldehydes and ketones are derived from alkanes by replacing “-e” with “-al” and “-one,” respectively. The longest carbon chain is numbered starting from the aldehyde or ketone carbon, and substituents are prefixed alphabetically with position numbers.